BFRL Publications - Gilman, J. W.

Gilman, J. W.

• Characterization of Flame Retarded Polymer Combustion Chars by Solid-State 13C and 29Si NMR and EPR.
  Polymer Preprints, Vol. 38, No. 1, 802-803, April 1997 AND Fire and Materials, Vol. 22, No. 2, 61-67, March/April 1998,
  Gilman, J. W.; Lomakin, S. M.; Kashiwagi, T.; VanderHart, D. L.; Nagy, V.
• Characterization of Flame Retarded Polymer Combustion Chars by Solid-State 13C and 29Si NMR and EPR.
  Polymer Preprints, Vol. 38, No. 1, 802-803, April 1997 AND Fire and Materials, Vol. 22, No. 2, 61-67, March/April 1998,
  Gilman, J. W.; Lomakin, S. M.; Kashiwagi, T.; VanderHart, D. L.; Nagy, V.
• Char Enhancing Approaches to Flame Retarding Polymers.
  Chemistry and Technology of Polymer Additives. Chapter 8. 1999, Blackwell Science Inc., Malden, MA, Ak-Malaika, S.; Golovoy, A.; Wilkie, C. A., Editor(s)(s), 135-150 pp, 1999.
  Gilman, J. W.; Kashiwagi, T.; Harris, R. H., Jr.; Lomakin, S. M.; Lichtenhan, J. D.; Bolf, A.; Jones, P.
• Char Enhancing Approaches to Flame Retarding Polymers.
  ADDITIVES'98 Meeting. Proceedings. February 1998, Orlando, FL, 1-20 pp, 1998.
  Gilman, J. W.; Kashiwagi, T.; Harris, R. H., Jr.; Lomakin, S. M.; Lichtenhan, J. D.; Bolf, A.; Jones, P.
• Char Enhancing Approaches to Polymer Flammability: The Effect of Radicals on Magic Angle Spinning 13C NMR of Chars.
  NISTIR 5904; October 1996.National Institute of Standards and Technology. Annual Conference on Fire Research: Book of Abstracts. October 28-31, 1996, Gaithersburg, MD, 133-134 pp, 1996.
  Gilman, J. W.; Lomakin, S. M.; Kashiwagi, T.; VanderHart, D. L.; Nagy, V.
• Cyanate Ester Clay Nanocomposites: Synthesis and Flammability Studies.
  Evolving and Revolutionary Technologies for the New Millennium. International SAMPE Symposium/Exhibition, 44th. Proceedings. Society for the Advancement of Material and Process Engineering (SAMPE). May 23-27, 1999, Long Beach, CA, 1408-1423 pp, 1999.
  Gilman, J. W.; Harris, R. H., Jr.; Hunter, D.
• Development of a Continuous Flow Flame Test Extruder for High-Throughput Formulation and Screening of Flame Retardants and More Fire Resistant Materials.
  Fire Safety Developments Emerging Needs, Product Developments, Non-Halogen FR's, Standards and Regulations. Proceedings. Fire Retardant Chemicals Association. March 12-15, 2000, Washington, DC, Fire Retardant Chemicals Assoc., Lancaster, PA, 1-5 pp, 2000.
  Nyden, M. R.; Gilman, J. W.
• Development of High Throughput Methods for Polymer Nanocomposite Research.
  New Century of FR Compounding. Fall Conference. Proceedings. Fire Retardant Chemicals Association. October 20-22, 2002, Cleveland, OH, Fire Retardant Chemicals Assoc., Lancaster, PA, 27-45 pp, 2002.
  Gilman, J. W.; Davis, R. D.; Nyden, M. R.; Kashiwagi, T.; Shields, J. R.; Demory, W.
• Environmentally Safe Fire Retardants for Polymeric Materials. Part 1. Silica Gel: Potassium Carbonate Additive.
  Materials and Process Challenges: Aging Systems, Affordability, Alternative Applications. SAMPE Symposium and Exposition, 41st Proceedings. Volume 41. Book 1. Society for the Advancement of Material and Process Engineering (SAMPE). March 24-28, 1996, Anaheim, CA, 708-713 pp, 1996.
  Gilman, J. W.; Kashiwagi, T.; Lomakin, S. M.
• Fire Retardant Additives for Polymeric Materials. Part 1. Char Formation From Silica Gel-Potassium Carbonate.
  NISTIR 6030; June 1997.U.S./Japan Government Cooperative Program on Natural Resources (UJNR). Fire Research and Safety. 13th Joint Panel Meeting. Volume 2. March 13-20, 1996, Gaithersburg, MD, Beall, K. A., Editor(s), 261-270 pp, 1997.Fire and Materials, Vol. 21, No. 1, 23-32, 1997.
  Gilman, J. W.; Ritchie, S. J.; Kashiwagi, T.; Lomakin, S. M.
• Fire Safe Materials Project at NIST.
  NISTIR 6588; November 2000.U.S./Japan Government Cooperative Program on Natural Resources (UJNR). Fire Research and Safety. 15th Joint Panel Meeting. Volume 1. Proceedings. March 1-7, 2000, San Antonio, TX, Bryner, S. L., Editor(s), 71-79 pp, 2000.
  Kashiwagi, T.; Butler, K. M.; Gilman, J. W.
• Flame Retardant Mechanism of Silica Gel/Silica.
  Recent Advances in Flame Retardancy of Polymeric Materials: Materials, Applications, Research and Industry Developments, Markets. Volume 11. Business Communications Co., Inc. (BCC). May 22-24, 2000, Stamford, CT, Business Communications Co., Inc., Norwalk, CT, Lewin, M., Editor(s), 58-83 pp, 2000.Fire and Materials, Vol. 24, No. 6, 277-289, November/December 2000.
  Kashiwagi, T.; Gilman, J. W.; Butler, K. M.; Harris, R. H., Jr.; Shields, J. R.; Asano, A.
• Flammability and Thermal Stability Studies of Polymer Layered-Silicate (Clay) Nanocomposites.
  Applied Clay Science, Vol. 15, 31-49, 1999.
  Gilman, J. W.
• Flammability and Thermal Stability Studies of Polymer Layered-Silicate (Clay) Nanocomposites. Part 2.
  Flame Retardancy, 10th Annual BCC (Business Communications Co., Inc.) Conference. Proceedings. May 24-26, 1999, Stamford, CT, Business Communications Co., Inc., Norwalk, CT, 1-11 pp, 1999.
  Gilman, J. W.; Morgan, A. B.; Giannelis, E. P.; Wuthenow, M.; Manias, E.
• Flammability of Polymer Clay Nanocomposites Consortium: Year One Annual Report.
  NISTIR 6531; 55 p. July 2000.
  Gilman, J. W.; Kashiwagi, T.; Morgan, A. B.; Harris, R. H., Jr.; Brassell, L. D.; VanLandingham, M. R.; Jackson, C. L.
• Flammability of Polymer-Clay Nanocomposites.
  Fire Safety Developments Emerging Needs, Product Developments, Non-Halogen FR's, Standards and Regulations. Proceedings. Fire Retardant Chemicals Association. March 12-15, 2000, Washington, DC, 25-39 pp, 2000.
  Morgan, A. B.; Gilman, J. W.; Kashiwagi, T.; Jackson, C. L.
• Flammability of Polystyrene-Clay Nanocomposites.
  Polymeric Materials Science and Engineering, Vol. 83, 53-54, 2000.
  Morgan, A. B.; Gilman, J. W.; Harris, R. H., Jr.; Jackson, C. L.; Wilkie, C. A.; Zhu, J.
• Flammability of Polystyrene Layered Silicate (Clay) Nanocomposites: Carbonaceous Char Formation.
  Fire and Materials, Vol. 26, No. 6, 247-253, November/December 2002.
  Morgan, A. B.; Harris, R. H., Jr.; Kashiwagi, T.; Chyall, L. J.; Gilman, J. W.
• Flammability Properties of Phosphine Oxide Copolymers and of Commodity Polymers With New Flame Retardant Additives.
  Tomorrow's Trends in Fire Retardant Regulations, Testing, Applications and Current Technologies. Fall Conference. Proceedings. October 13-16, 1996, Naples, FL, 1-23 pp, 1996.
  Kashiwagi, T.; Gilman, J. W.; McGrath, J. E.; Wan, I. Y.
• Flammability Properties of Polymer-Layered-Silicate Nanocomposites, Polypropylene and Polystyrene Nanocomposites.
  Chemistry of Materials, Vol. 12, No. 7, 1866-1873, July 17, 2000.
  Gilman, J. W.; Jackson, C. L.; Morgan, A. B.; Harris, R. H., Jr.; Manias, E.; Giannelis, E. P.; Wuthenow, M.; Hilton, D.; Phillips, S. H.
• Flammability Studies of New Cyanate Ester Resins.
  Evolving Technologies for the Competitive Edge. SAMPE Symposium and Exhibition, 42nd International Proceedings. Volume 42. Book 2. Society for the Advancement of Material and Process Engineering (SAMPE). Proceedings. May 4-8, 1997, Anaheim, CA, Haulik, T.; Bailey, V.; Burton, R., Editor(s)(s), 1052-1061 pp, 1997.
  Gilman, J. W.; Harris, R. H., Jr.; Brown, J. E.
• Flammability Studies of Polymer Layered Silicate (Clay) Nanocomposites.
  NISTIR 6242; October 1998.National Institute of Standards and Technology. Annual Conference on Fire Research: Book of Abstracts. November 2-5, 1998, Gaithersburg, MD, Beall, K. A., Editor(s), 37-38 pp, 1998.
  Gilman, J. W.; Kashiwagi, T.; Nyden, M. R.; Brown, J. E.; Jackson, C. L.; Lomakin, S. M.; Giannelis, E. P.; Manias, E.
• Flammability Studies of Polymer Layered Silicate Nanocomposites.
  Materials and Process Affordability Keys to the Future. SAMPE Symposium and Exhibition, 43rd International Proceedings. Volume 43. Book 1 of 2 Books. Society for the Advancement of Material and Process Engineering (SAMPE). May 31-June 4, 1998, Anaheim, CAe, Kliger, H. S.; Rasmussen, B.; Pilato, L. A.; Tolle, T. B., Editor(s)(s), 1053-1066 pp, 1998.
  Gilman, J. W.; Kashiwagi, T.; Brown, J. E.; Lomakin, S. M.; Giannelis, E. P.; Manias, E.
• Flammability Studies of Polymer Layered Silicate Nanocomposites: Polyolefin, Epoxy, and Vinyl Ester Resins.
  Chemistry and Technology of Polymer Additives. Chapter 14. 1999, Blackwell Science Inc., Malden, MA, Ak-Malaika, S.; Golovoy, A.; Wilkie, C. A., Editor(s)(s), 249-265 pp, 1999.
  Gilman, J. W.; Kashiwagi, T.; Nyden, M. R.; Brown, J. E. T.; Jackson, C. L.; Lomakin, S. M.; Giannelis, E. P.; Manias, E.
• Further Studies on Fire Retardant Polystyrene by Friedel-Crafts Chemistry.
  Polymer Degradation and Stability, Vol. 66, 373-378, 1999.
  Wang, Z.; Jiang, D. D.; Wilkie, C. A.; Gilman, J. W.
• High Throughput Flammability Characterization Using Gradient Heat Flux Fields.
  Journal of ASTM International, Vol. 2, No. 9, October 2005.
  Gilman, J. W.; Davis, R. D.; Shields, J. R.; Harris, R. H., Jr.
• High Throughput Methods for Polymer Nanocomposites Research: Extrusion, NMR Characterization and Flammability Property Screening.
  Journal of Materials Science, Vol. 38, 4451-4460, 2003.
  Gilman, J. W.; Bourbigot, S.; Shields, J. R.; Nyden, M. R.; Kashiwagi, T.; Davis, R. D.; Vanderhart, D. L.; Demory, W.; Wilkie, C. A.; Morgan, A. B.; Harris, J.; Lyon, R. E.
• Improved Thermal Stability of Organically Modified Layered Silicates.
  Clays and Clay Minerals, Vol. 52, No. 2, 171-179, 2004.
  Davis, R. D.; Gilman, J. W.; Sutto, T. E.; Callahan, J. H.; Trulove, P. C.; DeLong, H. C.
• Investigation of Nanodispersion in Polystyrene-Montmorillonite Nanocomposites by Solid-State NMR.
  Journal of Polymer Science: Part B: Polymer Physics, Vol. 41, No. 24, 3188-3213, December 15, 2003.
  Bourbigot, S.; Vanderhart, D. L.; Gilman, J. W.; Awad, W. H.; Davis, R. D.; Morgan, A. B.; Wilkie, C. A.
• Molecular Dynamics Simulations of the Thermal Degradation of Nano-Confined Polypropylene.
  Materials Today, Vol. 1, No. 4, 12-14, December 1998 AND Computational and Theoretical Polymer Science, Vol. 7, No. 3/4, 191-198, 1997,
  Nyden, M. R.; Gilman, J. W.
• Molecular Dynamics Simulations of the Thermal Degradation of Nano-Confined Polypropylene.
  Materials Today, Vol. 1, No. 4, 12-14, December 1998 AND Computational and Theoretical Polymer Science, Vol. 7, No. 3/4, 191-198, 1997,
  Nyden, M. R.; Gilman, J. W.
• Nanocomposites: A Revolutionary New Flame Retardant Approach.
  Evolving Technologies for the Competitive Edge. SAMPE Symposium and Exhibition, 42nd International Proceedings. Volume 42. Book 2. Society for the Advancement of Material and Process Engineering (SAMPE). May 4-8, 1997, Anaheim, CA, Haulik, T., Bailey, V., Burton, R., Editors, 1078-1089 pp, 1997 AND Fire Retardancy of Polymeric Materials, 6th European Meeting. F.R.P.M. '97. Proceedings. Lectures. LCAPS, Ecole Nationale Superieure de Chimie de Lille (ENSCL) and Centre de Recherche et d'Etude sur les Procedes d'Ignifugation des Materiaux (CREPIM). Lille, France. September 24-26, 1997, 19-20 pp, 1997, 1997.
  Gilman, J. W.; Kashiwagi, T.; Lichtenhan, J. D.
• Nanocomposites: A Revolutionary New Flame Retardant Approach.
  SAMPE Journal, Vol. 33, No. 4, 40-46, August 1997.
  Gilman, J. W.; Kashiwagi, T.; Lichtenhan, J. D.
• Nanocomposites: Radiative Gasification and Vinyl Polymer Flammability.
  Fire Retardancy of Polymers: The Use of Intumescence. 6th European Meeting. (FRPM'97). Proceedings. Special Publication No. 224. Organised Jointly by the Laboratoire de Chimie Analytique et de Physico-Chimie des Solides' de l'E.N.S.C. de Lille and the Centre de Recherche et d'Etude des Procedes d'Ignifugation des Materiaux. September 24-26, 1997, Lille, France, Royal Society of Chemistry, Cambridge, UK, LeBras, M.; Camino, G.; Bourbigot, S.; Delobel, R., Editor(s)(s), 203-221 pp, 1998.
  Gilman, J. W.; Kashiwagi, T.; Giannelis, E. P.; Manias, E.; Lomakin, S. M.; Lichtenhan, J. D.; Jones, P.
• New Approaches to the Development of Fire-Safe Materials.
  NISTIR 6465; 22 p. February 2000.
  Morgan, A. B.; Gilman, J. W.; Nyden, M. R.; Jackson, C. L.
• New Flame Retardant Additives.
  Fire Retardanty of Polymeric Materials, 6th European Meeting. F.R.P.M. '97. Proceedings. Invited Lectures. LCAPS, Ecole Nationale Superieure de Chimie de Lille (ENSCL) and Centre de Recherche et d'Etude sur les Procedes d'Ignifugation des Materlaux (CREPIM). September 24-26, 1997, Lille, France, Bourbigot, S.; LeBras, M.; Delobel, R., Editor(s)(s), 4-8 pp, 1997.
  Kashiwagi, T.; Gilman, J. W.; Nyden, M. R.
• New Flame Retardants Consortium: Flame Retardant Mechanism of Silica. Final Report.
  NISTIR 6357; 28 p. June 1999.
  Gilman, J. W.; Kashiwagi, T.; Nyden, M. R.; Harris, R. H., Jr.
• New Non-Halogenated Fire Retardant for Commodity and Engineering Polymers.
  PCT International Application; 7 p. 1997.
  Gilman, J. W.
• Past and Future of Public Flame Retardancy Research.
  International Fire Safety Conference. Spring Conference. Proceedings. Fire Retardant Chemicals Association (FRCA). March 11-14, 2001, San Francisco, CA, Fire Retardant Chemicals Assoc., Lancaster, PA, 93-106 pp, 2001.
  Gilman, J. W.
• Phenolic Cyanate Ester Clay Nanocomposites: Effect of Ammonium Ion Structure on Flammability and Nano-Dispersion.
  Polymeric Materials: Science and Engineering (PMSE). Spring Meeting. Volume 82. Proceedings. American Chemical Society (ASME). March 26-30, 2000, San Francisco, CA, American Chemical Society, Washington, DC, 276-277 pp, 2000.
  Gilman, J. W.; Harris, R. H., Jr.; Jackson, C. L.; Morgan, A. B.; Brassell, L. D.; Hunter, D. L.
• Polymer Combustion and New Flame Retardants.
  BCC Conference on Flame Retardancy, Seventh (7th) Annual. Proceedings. Business Communications Co., Inc. (BCC). May 20-22, 1996, Stamford, CT, 1-26 pp, 1996.
  Kashiwagi, T.; Hamins, A.; Steckler, K. D.; Gilman, J. W.
• Polymer Combustion and New Flame Retardants.
  BCC Conference on Flame Retardancy, Seventh (7th) Annual. Proceedings. Business Communications Co., Inc. (BCC). May 20-22, 1996, Stamford, CT, 1-26 pp, 1996.
  Kashiwagi, T.; Hamins, A.; Steckler, K. D.; Gilman, J. W.
• Polymer Film Applied to Glass: Effectiveness at Mitigating Damage from Flying Glass Due to Explosions.
  NISTIR 5779; 16 p. January 1996.
  Gilman, J. W.; Simiu, E.
• Polymer/Layered Silicate Nanocomposites from Thermally Stable Trialkylimidazolium-Treated Montmorillonite.
  Chemistry of Materials, Vol. 14, No. 9, 3776-3785, 2002.
  Gilman, J. W.; Awad, W. H.; Davis, R. D.; Shields, J. R.; Harris, R. H., Jr.; Davis, C. H.; Morgan, A. B.; Sutto, T. E.; Callahan, J.; Trulove, P. C.; DeLong, H. C.
• Polymer Layered-Silicate Nanocomposites: Polyamide-6, Polypropylene and Polystyrene.
  New Advances in Flame Retardant Technology. Proceedings. Fire Retardant Chemicals Association. October 24-27, 1999, Tucson, AZ, Fire Retardant Chemicals Assoc., Lancaster, PA, 9-22 pp, 1999.
  Gilman, J. W.; Morgan, A. B.; Harris, R. H., Jr.; Manias, E.; Giannelis, E. P.; Wuthenow, M.
• Polymer Layered Silicate Nanocomposites: Thermal Stability of Organic Cationic Treatments.
  Polymeric Materials Science and Engineering, Vol. 83, 59-60, 2000.
  Gilman, J. W.; Morgan, A. B.; Harris, R. H., Jr.; Trulove, P. C.; DeLong, H. C.; Sutto, T. E.
• Preceramic Additives as Fire Retardants for Plastics.
  U.S. Patent Application; 13 p. May 28, 1997.
  Lichtenhan, J. D.; Gilman, J. W.
• Preceramic Polymer Blends as Novel Environmentally Safe Fire Retardants.
  U.S. Provisional Patent Application; 8 p. November 1996.
  Lichtenhan, J. D.; Gilman, J. W.
• Preparation and Flame Resistance Properties of Revolutionary Self-Extinguishing Epoxy Nanocomposites Based on Layered Double Hydroxides.
  Polymer, Vol. 46, No. 22, 9314-9328, October 2005.
  Zammarano, M.; Franceschi, M.; Bellayer, S.; Gilman, J. W.; Meriani, S.
• Process for Preparation of Polyhedral Oligomeric Silsesquioxanes and Systhesis of Polymers Containing Polyhedral Oligomeric Silsesquioxane Group Segments.
  U.S. Patent 5,484,867; 8 p. January 16, 1996.
  Lichtenhan, J. D.; Gilman, J. W.; Feher, F. J.
• Processing Degradation of Polyamide 6/Montmorillonite Clay Nanocomposites and Clay Organic Modifier.
  Polymer Degradation and Stability, Vol. 79, 111-121, 2003.
  Davis, R. D.; Gilman, J. W.; Vanderhart, D. L.
• Recent Advances in Flame Retardant Polymer Nanocomposites.
  Fire and Materials 2001. 7th International Conference and Exhibition. Proceedings. Interscience Communications Limited. January 22-24, 2001, San Antonio, TX, 273-283 pp, 2001.
  Gilman, J. W.; Kashiwagi, T.; Morgan, A. B.; Harris, R. H., Jr.; Brassell, L. D.; Awad, W. H.; Davis, R. D.; Chyall, L.; Sutto, T.; Trulove, P. C.; DeLong, H.
• Silicon-Based Flame Retardants.
  Fire Retardancy of Polymeric Materials. Chapter 10, Marcel Dekker, Inc., New York, NY, Grand, A. F.; Wilkie, C. A., Editor(s), 353-389 p., 2000.
  Kashiwagi, T.; Gilman, J. W.
• Solid State NMR Characterization and Flammability of Styrene-Acrylonitrile Copolymer Montmorillonite Nanocomposite.
  Polymer, Vol. 45, No. 22, 7627-7638, October 2004.
  Bourbigot, S. P.; Vanderhart, D. L.; Gilman, J. W.; Bellayer, S.; Stretz, H.; Paul, D. R.
• Styrene-Acrylonitrile Copolymer Montmorillonite Nanocomposite: Processing, Characterization and Flammability.
  Chapter 13;Fire Retardancy of Polymers. New Applications of Mineral Fillers. Chapter 13, Royal Society of Chemistry, Cambridge, UK, 177-186 p., 2005.
  Gilman, J. W.; Bourbigot, S.; Bellayer, S.; Stretz, H.; Paul, D. R.
• Synthesis of New Cyanate Ester Resins for Polymer Flammability Studies.
  ANTEC '96 Conference. Proceedings. Society of Plastics Engineers. May 5-9, 1996, Indianapolis, IN, 1996.
  Gilman, J. W.; Brown, J. E.; Oliver, K. D.
• Thermal Decomposition Chemistry of Poly(Vinyl Alcohol): Char Characterization.
  NISTIR 5499; September 1994.National Institute of Standards and Technology. Annual Conference on Fire Research: Book of Abstracts. October 17-20, 1994, Gaithersburg, MD, 101-102 pp, 1994.
  Gilman, J. W.; Kashiwagi, T.; VanderHart, D. L.
• Thermal Decomposition Chemistry of Poly(vinyl alcohol).
  Chapter 11; ACS Symposium Series 599;American Chemical Society. Fire and Polymers II: Materials and Tests for Hazard Prevention. National Meeting, 208th. ACS Symposium Series 599. August 21-26, 1994, Washington, DC, American Chemical Society, Washington, DC, Nelson, G. L., Editor(s), 161-185 pp, 1995.
  Gilman, J. W.; VanderHart, D. L.; Kashiwagi, T.
• Thermolysis of Polyhedral Oligomeric Silsesquioxane (POSS) Macromers and POSS-Siloxane Copolymers.
  Chemistry of Materials, Vol. 8, No. 6, 1250-1259, 1996.
  Mantz, R. A.; Jones, P. F.; Chaffee, K. P.; Lichtenhan, J. D.; Gilman, J. W.; Ismail, I. M. K.; Burmeister, M. J.